This vent window latch removal procedure should apply to similar 1962 to 1965 Mopars.
The top picture shows the front doors vent window, also known as a quarterlight, and the latch used to secure the window shut, as viewed from the outside of the car.
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The slot in the vent latch is for a screwdriver since the slotted piece is a nut. The carriage bolt is threaded and it and the slotted nut hold the inner and outer chrome trim pieces together, sandwiching the glass.